Journal of Siberian Federal University. Mathematics & Physics / NEXAFS and FTIR Spectroscopy of Co-doped SrBi2Nb2O9

Full text (.pdf)
Issue
Journal of Siberian Federal University. Mathematics & Physics. 2022 15 (1)
Authors
Zhuk, Nadezhda A.; Ipatova, Elena U.; Makeev, Boris A.; Nekipelov, Sergey V.; Beznosikov, Dmitriy S.; Rychkova, Lubov V.
Contact information
Zhuk, Nadezhda A.: Syktyvkar State University Syktyvkar, Russian Federation; ; Ipatova, Elena U.: Institute of Chemistry of the Komi Scientific Center Ural Branch RAS Syktyvkar, Russian Federation; ; Makeev, Boris A.: Institute of Geology of the Komi Scientific Center Ural Branch RAS Syktyvkar, Russian Federation; ; Nekipelov, Sergey V.: nstitute of Physics and Mathematics of the Komi Science Center UB RAS Syktyvkar, Russian Federation; ; Beznosikov, Dmitriy S.: Federal State Unitary Enterprise «General Radio Frequency Centre» Syktyvkar, Russian Federation; ; Rychkova, Lubov V.: Pitirim Sorokin Syktyvkar State University Syktyvkar, Russian Federation;
Keywords
Aurivillius phases; IR spectroscopy; NEXAFS; cobalt; NEXAFS
Abstract

The solid-phase ceramic method was used to synthesize cobalt-containing solid solutions based on SrBi2Nb2O9. NEXAFS (Near Edge X-ray Absorption Fine Structure) and IR spectroscopy were used to study the electronic state of cobalt atoms in solid cross-links with a layered perovskite-like structure. It was found that cobalt atoms are in high-spin states of Co(III) and, mainly, Co(II) in an octahedral oxygen environment

Pages
5–12
DOI
10.17516/1997-1397-2022-15-1-5-12
Paper at repository of SibFU
https://elib.sfu-kras.ru/handle/2311/144958