Journal of Siberian Federal University. Chemistry / Comparison of the Sorption Capacitance of Ion-Lithium Graphite, Fullerene-Lithium Anode

Full text (.pdf)
Issue
Journal of Siberian Federal University. Chemistry. 2013 6 (2)
Authors
Leonova, Taisia A.; Vnukova, Natalia G.; Osipova, Irina V.; Glushenko, Gari A.; Tomashevich, Evgenie V.; Churilov, Grigory N.
Contact information
Leonova, Taisia A.: Siberian Federal University, 79 Svobodny, Krasnoyarsk, 660041 Russia;; Vnukova, Natalia G.: Siberian Federal University, 79 Svobodny, Krasnoyarsk, 660041 Russia; Institute of Physics SB RAS, 50 Akademgorodok, Krasnojarsk, 660036 Russia; Krasnoyarsk State Pedagogical University named after V. P. Astafiev, 89 Adi Lebedevoi Str., Krasnoyarsk, 660049 Russia;; Osipova, Irina V.: Siberian Federal University, 79 Svobodny, Krasnoyarsk, 660041 Russia; Institute of Physics SB RAS, 50 Akademgorodok, Krasnojarsk, 660036 Russia;; Glushenko, Gari A.: Krasnoyarsk State Pedagogical University named after V. P. Astafiev, 89 Adi Lebedevoi Str., Krasnoyarsk, 660049 Russia;; Tomashevich, Evgenie V.: Institute of Chemistry and Chemical Technology SB RAS, 50/24 Akademgorodok, Krasnojarsk, 660036 Russia;; Churilov, Grigory N.: Siberian Federal University, 79 Svobodny, Krasnoyarsk, 660041 Russia; Institute of Physics SB RAS, 50 Akademgorodok, Krasnojarsk, 660036 Russia; Krasnoyarsk State Pedagogical University named after V. P. Astafiev, 89 Adi Lebedevoi Str., Krasnoyarsk, 660049 Russia;
Keywords
lithium-ion battery; fulleride-lithium; turbostratic graphite; specific capacitance
Abstract

The comparative analysis of the lithium-ion batteries discharge characteristics was carried out. The negative electrodes were produced from composite film fulleride-lithium, plates of hexagonal graphite and plates of turbostratic graphite. The metallic lithium plates were used as positive electrodes in all considered batteries. It was shown that the maximum value of discharge current was achieved with using turbostratic graphite as anode. The active layer of lithium ion intercalations in turbostratic graphite was 600 nm according to X-ray photoelectron spectroscopy results. For the active area the average specific capacitance was 244 mA · h / g, while for the film of fullerene-Li – 221 mA · h / g. By X-ray analysis it was determined that structure of turbostratic graphite was stable during recycling, when the hexagonal graphite was destroyed.

Pages
210-217
Paper at repository of SibFU
https://elib.sfu-kras.ru/handle/2311/9826